INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016
open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15
Synthesis, Spectroscopic, Thermal and Electrical Studies of Some Transition Metal Coordination Polymers
Authors Name:
A.D.Bansod
Unique Id:
IJSDR2107036
Published In:
Volume 6 Issue 7, July-2021
Abstract:
Coordination polymers of Mn(II),Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) coordination polymers of Schiff base ligand (TDINH) derived from Terephthaladehyde and Isoniazid have been prepared. The ligand is characterized by elemental analyses, IR and electronic spectra, magnetic susceptibility measurements and thermogravimetric analysis. Thermogravimetric analysis decomposition behaviors of all the coordination polymers were studied using thermogravimetric analysis in nitrogen atmosphere. The octahedral geometry have been suggested for Mn(II), Fe(II), Co(II) and Ni(II) coordination polymers, square planar geometry to Cu((II) where as tetrahedral for Zn(II) and Cd(II) coordination polymers .Thermal data have been analyzed for kinetic parameters by both Coat-Redfern and Broido methods. The solid state electrical conductivity of ligand and its coordination polymers has been measured in the temperature range 313-413K and coordination polymers are found to show semiconducting behavior.
Keywords:
Schiff base, Thermogravimetric and TG/TGA, Electrical Conductivity
Cite Article:
"Synthesis, Spectroscopic, Thermal and Electrical Studies of Some Transition Metal Coordination Polymers", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.6, Issue 7, page no.226 - 230, July-2021, Available :http://www.ijsdr.org/papers/IJSDR2107036.pdf
Downloads:
000337070
Publication Details:
Published Paper ID: IJSDR2107036
Registration ID:193477
Published In: Volume 6 Issue 7, July-2021
DOI (Digital Object Identifier):
Page No: 226 - 230
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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