Kinetic and Viscometric studies of oxidation of Sucrose and Fructose by Vanadium (V) in Sulphuric acid medium
BHUWAN CHANDRA
, DEEPESH KUMAR TAMTA , NAVEEN CHANDRA , NARAIN DUTT KANDPAL
Redox reactions, Sugars, Vanadium (V), Complex ion, Viscosity, Sulphuric acid
Investigations were carried out on the oxidation of fructose and sucrose by Vanadium (V) in aqueous sulphuric acid at temperature 298 K.The kobs increases linearly with concentration of both the sugars. The effect of viscosity of the aqueous sulphuric acid on rate constant has also been investigated to make a study of viscosity of the medium on the rate of oxidation. In case of both the substrates the rate of oxidation follow the linear relationship with the viscosity of the reaction medium with linearity coefficient greater than 0.98.The reaction was first order with respect to substrates and accelerated with the increase in the sulphuric acid concentration. The proposed mechanism of the oxidation based on the formation of the vanadium (V) complex ion leads to the formation of free radical of the substrates.
"Kinetic and Viscometric studies of oxidation of Sucrose and Fructose by Vanadium (V) in Sulphuric acid medium ", IJSDR - International Journal of Scientific Development and Research (www.IJSDR.org), ISSN:2455-2631, Vol.7, Issue 11, page no.1243 - 1250, November-2022, Available :https://ijsdr.org/papers/IJSDR2211187.pdf
Volume 7
Issue 11,
November-2022
Pages : 1243 - 1250
Paper Reg. ID: IJSDR_202783
Published Paper Id: IJSDR2211187
Downloads: 000347257
Research Area: Chemistry
Country: Almora, Uttarakhand, India
ISSN: 2455-2631 | IMPACT FACTOR: 9.15 Calculated By Google Scholar | ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 9.15 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator
Publisher: IJSDR(IJ Publication) Janvi Wave
