Kinetics of Oxidation of Aldehyde by Piperidinium Chlorochromate

Sandeep Kumar Chaurasia , Saras Tiwari

acetaldehyde, propanaldehyde, Piperidinium chlorochromate, kinetics, oxidation

Oxidation of aliphatic aldehydes (acetaldehyde and propanaldehyde) by piperidinium chlorochromate (Pipcc.) in aqueous acetic acid medium proceeds a mechanism involving transfer of hydride ion from aldehyde to pipcc. (oxidant) through an intermediate complex. The reaction is sensitized by hydrogen ions. The oxidation of aldehydes indicated an α-C-H bond cleavage in the rate-determining step leads to formation of corresponding carboxylic acids. The reaction is first-order in Pipcc. The structure-reactivity correlation with thermodynamic parameters and non-kinetic parameters was suggested.

Published Paper   E-Certificate

"Kinetics of Oxidation of Aldehyde by Piperidinium Chlorochromate", IJSDR - International Journal of Scientific Development and Research (www.IJSDR.org), ISSN:2455-2631, Vol.8, Issue 7, page no.867 - 871, July-2023, Available :https://ijsdr.org/papers/IJSDR2307129.pdf

Volume 8 Issue 7, July-2023

Pages : 867 - 871

Paper Reg. ID: IJSDR_207890

Published Paper Id: IJSDR2307129

Downloads: 000347215

Research Area: Engineering

Country: -, -, India

Published Paper PDF: https://ijsdr.org/papers/IJSDR2307129

Published Paper URL: https://ijsdr.org/viewpaperforall?paper=IJSDR2307129

ISSN: 2455-2631 | IMPACT FACTOR: 9.15 Calculated By Google Scholar | ESTD YEAR: 2016

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