Oxidation Kinetics of Some Cyclonols by N-bromosuccinimide in Aqueous Acetic Acid and Micellar medium
Dheerendra Kumar Shukla
, Umesh Kumar Vishwakarma
N-bromosuccinimide, cycloheptanol, cyclooctanol, cetyltrimethlammonium- bromide (CTAB), oxidation
The kinetic oxidation of cycloheptanol and cyclooctanol were described with an emphasis of correlation of structure and reactivity. The reaction were first-order with respect to loss of [NBS] N-bromosuccinimide and reaction are [H+] that follow kobs = a+b [H+]. However, Michaelis-Menten type kinetics were observed for the cyclonols. The micellar CTAB exhibited the existence of ternary complex behaviours between oxidant species and substrate at transition state. Based on kinetic data, thermodynamic parameters and reacting species HOBr of oxidant with 1:1 stoichiometry a mechanism was pastulated with the expulsion of α-H hydride anion.
"Oxidation Kinetics of Some Cyclonols by N-bromosuccinimide in Aqueous Acetic Acid and Micellar medium", IJSDR - International Journal of Scientific Development and Research (www.IJSDR.org), ISSN:2455-2631, Vol.8, Issue 7, page no.876 - 880, July-2023, Available :https://ijsdr.org/papers/IJSDR2307131.pdf
Volume 8
Issue 7,
July-2023
Pages : 876 - 880
Paper Reg. ID: IJSDR_207892
Published Paper Id: IJSDR2307131
Downloads: 000347255
Research Area: Chemistry
Country: -, -, India
ISSN: 2455-2631 | IMPACT FACTOR: 9.15 Calculated By Google Scholar | ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 9.15 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator
Publisher: IJSDR(IJ Publication) Janvi Wave
